Nucleophile-induced transformations of 1,2,4-triazines. 3. Anrorc constriction of the ring in the reaction of 6-aryl-3-dimethylamino-1,2,4-triazine 4-oxides with KCN
β Scribed by V. N. Kozhevnikov; D. N. Kozhevnikov; V. L. Rusinov; O. N. Chupakhin
- Book ID
- 105534708
- Publisher
- Springer US
- Year
- 1999
- Tongue
- English
- Weight
- 232 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0009-3122
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## Abstract The reaction of 3βchloroβ6βphenylβ1,2,4βtriazine **1a** with carbon nucleophiles **2aο£Ώd** bearing a cyano substituent at a carbanionic center has been studied. In all reactions the formation of the corresponding 3βaminopyridazines **3aο£Ώd** takes place via ANRORC mechanism involving addi