The present paper reports the achievement of the rotating-frame analog of spin-locking and its application to the precise measurements of the spin-lattice relaxation time T(1DR) in the doubly rotating frame. After the magnetization is aligned along the resonant RF field H(1), a pulse sequence of a l
Nuclear Quadrupole Coupling, Spin-Rotation, and Spin-Spin Interaction in the Rotational Spectrum of Ethinylisocyanide
✍ Scribed by M. Kruger; W. Stahl; H. Dreizler
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 264 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The rotational (J=1-0) transitions of nine different isotopomers of ethinylisocyanide. (\mathrm{H} \cdots \mathrm{C} \equiv \mathrm{C}-\mathrm{NC}), were measured with high resolution using a pulsed molecular beam microwave Fourier transform (MB-MWFT) spectrometer. The analysis of the complex hyperfine patterns yielded nuclear quadrupole, spin-rotation, and spin-spin interaction constants. o 1993 Academic Press. Inc.
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