lsF NMR linewidth studies of polycrystalhe lead fluoride (PbF3 in the femperature range -50% to L9O"C reveal line-narrowing above -10Β°C. This is analysed in tens of vacancy diffusion. Lead fluoride (PbFZ) is known to have o+-~orhombic structure f I] up to 200Β°C above which it undergoes a phase trans
Nuclear magnetic resonance study of 19F motion in CsPbF3
β Scribed by V.M. Bouznik; Yu.N. Moskvich; V.N. Voronov
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 298 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The lgF nuclear magnetic relaxation times and line-widths have been measured in polycrystalline CsPbF3 imthe temperature range from -1.5D Lo +300Β°C. The observed motional nxrowing of the NhlR line-width at low temperatures and the tempernture dependences of the rehxation times are nnalysed in terms of LI hi$ vacancy diffusion cf the F-ions.
π SIMILAR VOLUMES
relaxation time measurements as a function of temperature in pure and NaF doped samples of PbF2 xe reported. The doped samples exhibit pronounced motional narrowing at low temperatures due to tk lligh 19F diffusivity.
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract __In vivo__ ^19^F NMR measurements of trifluorinated neuroleptics in the rat brain were made using a 13 Γ 18 mm surface coil at 4.7 T. The signal of fluphenazine was obtained within 8β15 min from brains of living rats treated chronically with drug doses of 5β30 mg/kg. Following the intr