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Nuclear Magnetic Resonance Studies on Steroids. III. 1 Steroidal Epoxides and Episulfides

โœ Scribed by Tori, Kazuo; Komeno, Taichiro; Nakagawa, Toshio


Book ID
120501764
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
719 KB
Volume
29
Category
Article
ISSN
0022-3263

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โœ Mario D. Gonzalez; Gerardo Burton ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 556 KB

The '3C N M R spectra of sixteen 4-ene-3-keto-and 1,4-diene-3-keto corticosteroids are described. Substituent shifts and the effect of added methanol-d, are reported, and conformational distortions and intramolecular hydrogen bonding are analysed based on these data. DISCUSSION ## Substituent eff