Nuclear magnetic resonance studies of the formation of tertiary alkyl complexes of iron(III) porphyrins and their reactions with dioxygen
β Scribed by Balch, Alan L.; Hart, Rebecca L.; Latos-Grazynski, Lechoslaw; Traylor, Teddy G.
- Book ID
- 126182819
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 874 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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## The reaction of toluene solutions of FeTPPCl with RSH (R = CH3 or (CH&') in the presence of pyridine has been studied by epr and electronic spectra. The reaction results in the reduction of FeTPPCl to FeTPP(Py)2 and the oxidation of RSH to R&. Kinetic data obtained for the reaction shows the obse
## Abstract Addition of aryl Grignard reagents to an iron(III) tetraphenylporphyrin Ο cation radical, [(TPPβ )Fe^III^Cl] (SbCl~6~), in dichloromethane solution at 202 K yields a mixture of Οβphenyl iron(IV) tetraphenylporphyrin, [(TPP)Fe^IV^(Ph)] (SbCl~6~), and Οβphenyl iron(III) tetraphenylporphyri