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Identification of intermediates and products in the reaction of porphyrin iron(III) alkyl complexes with dioxygen

โœ Scribed by Arasasingham, Ramesh D.; Balch, Alan L.; Latos-Grazynski, L.


Book ID
126271121
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
267 KB
Volume
109
Category
Article
ISSN
0002-7863

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โœ Bradford B. Wayland; James C. Swartz ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 497 KB

## The reaction of toluene solutions of FeTPPCl with RSH (R = CH3 or (CH&') in the presence of pyridine has been studied by epr and electronic spectra. The reaction results in the reduction of FeTPPCl to FeTPP(Py)2 and the oxidation of RSH to R&. Kinetic data obtained for the reaction shows the obse