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Nuclear Magnetic Resonance Spectroscopy. Ring Inversion in 3,5,7-Cyclooctatrienone 1a

โœ Scribed by Ganter, Camille; Pokras, Sanford M.; Roberts, John D.

Book ID
127168447
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
282 KB
Volume
88
Category
Article
ISSN
0002-7863

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โœ Maurice St-Jacques; Roland Prud'homme ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 197 KB

The energy barriers to ring inversion of 3,5,7-cyclooctatrienone (I) (11, and ~i~-l,2-dibromo-3,5,jr-cyclooctatriene (II) (2) have been determined by proton magnetic resonance (pmr) spectroscopy. We wish to report that the parent compound, 1,3,5-cyclooctatriene (III)\*, has an appreciably lower inve