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Nuclear magnetic resonance studies of conformation and ring inversion in the [3.3]paracyclophane system

✍ Scribed by Anet, Frank A. L.; Brown, Mary A.


Book ID
126974478
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
379 KB
Volume
91
Category
Article
ISSN
0002-7863

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Nuclear magnetic resonance study of ring
✍ Maurice St-Jacques; Roland Prud'homme πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 197 KB

The energy barriers to ring inversion of 3,5,7-cyclooctatrienone (I) (11, and ~i~-l,2-dibromo-3,5,jr-cyclooctatriene (II) (2) have been determined by proton magnetic resonance (pmr) spectroscopy. We wish to report that the parent compound, 1,3,5-cyclooctatriene (III)\*, has an appreciably lower inve