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Nuclear magnetic resonance of Zn(II) complexes with 2,2′-bipyridine

✍ Scribed by B. Jeżowska-Trzebiatowska; H. Kozłowski; L. Latos-Grażyński; T. Kowalik

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
305 KB
Volume
30
Category
Article
ISSN
0009-2614

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✦ Synopsis

The complexes Zn(bipy)gz zmd Zn(bipy)zQz as well as 2,2'-bipyridyl in aqueous'solution !DzO) have been e.xamined by the NMR method. The presence of the monoutionic bipy D+form in aqueous bipyridyl solution hu b-eed found-The changes of chemical shifts of bipyridyl protons for complexes Zn(bipy)sQz and Zn(bipy)& have conkned explicitly the es.sential influence of diamagnetic &rents on the NMR spectium of Zn(bipy)3&.

The comparison of the spectrn of 2,2'bipyridyl (in CHsOH) and of Zn(bipy)Clz may also suggest the presence of the nonbonding metal-proton 6 interaction.

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