NQR studies of gallium and bismuth trichlorides complexes with n- and Π -donors.
✍ Scribed by L.A. Popkova; E.N. Guryanova; A.F. Volkov
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 332 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0022-2860
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## Abstract Intensely coloured, extremely moisture sensitive complexes [VOCl~3~(L)] (L = pyridine, quinoline, Ph~3~PO, Ph~3~AsO, pyridine __N__‐oxide), [VOCl~3~(L)~2~] (L = pyridine, Me~3~PO, pyridine __N__‐oxide), [VOCl~3~(L–L)] [L–L = 2,2′‐bipyridyl, 1,10‐phenanthroline, Ph~2~P(O)CH~2~P(O)Ph~2~,
In the course of study on acetylene alcohols we have found that 1,1,6,&tetraphenylhexa-2,&.-diyne-1,6-diol (Ia) and 1,1,.!+,4-tetraphenylbut-2-yne-l,&-diol (IIa) formed crystalline \* complexes with various n-endkdonors by definite ratio. The most interesting complexes were derived from Ia and haloa