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Novel Synthesis of (Z)-Difluoroacrylates via a Highly Stereoselective Addition—Elimination Reaction.

✍ Scribed by Shigeyuki Yamada; Mayumi Noma; Tsutomu Konno; Takashi Ishihara; Hiroki Yamanaka

Publisher
John Wiley and Sons
Year
2006
Weight
34 KB
Volume
37
Category
Article
ISSN
0931-7597

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Synthesis of Tricyclopolyprenols via a Radical Addition and a Stereoselective Elimination. Part 1. Methodology. -Based on smooth radical addition of the alkenes (III) to the iodide (II) without radical rearrangement, stereoselective elimination of H 2 O from the activated alcohols (V) and (IX), and