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Novel Synthesis of Alkenes via Triethylborane-Induced Free-Radical Reactions of Alkyl Iodides and β -Nitrostyrenes

✍ Scribed by Liu, Ju-Tsung; Jang, Yeong-Jiunn; Shih, Yuh-Kuo; Hu, Shin-Ru; Chu, Cheng-Ming; Yao, Ching-Fa

Book ID
120502444
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
99 KB
Volume
66
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Novel Synthesis of
ChemInform Abstract: Novel Synthesis of Alkenes via Triethylborane-Induced Free-Radical Reactions of Alkyl Iodides and β-Nitrostyrenes.
✍ Ju-Tsung Liu; Yeong-Jiunn Jang; Yuh-Kuo Shih; Shin-Ru Hu; Cheng-Ming Chu; Ching- 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Novel synthesis of alkenes via triethyla
Novel synthesis of alkenes via triethylaluminum-induced free radical reactions of alkyl iodides and β-nitrostyrenes
✍ Jing-Yuan Liu; Ju-Tsung Liu; Ching-Fa Yao 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 53 KB

Reactions of (E)-b-nitrostyrenes 1 with triethylaluminum (Et 3 Al) 2 and alkyl iodide (RI) 3, 4, or 5 in the presence of benzoyl peroxide in diethyl ether solution at room temperature to give 60-100% of the different (E)-alkenes 6, 7, or 8. Under similar conditions, 95% of 1-adamantyl-2-(4-methoxyph