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Novel synthesis of alkenes via triethylaluminum-induced free radical reactions of alkyl iodides and β-nitrostyrenes

✍ Scribed by Jing-Yuan Liu; Ju-Tsung Liu; Ching-Fa Yao

Book ID
104230586
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
53 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reactions of (E)-b-nitrostyrenes 1 with triethylaluminum (Et 3 Al) 2 and alkyl iodide (RI) 3, 4, or 5 in the presence of benzoyl peroxide in diethyl ether solution at room temperature to give 60-100% of the different (E)-alkenes 6, 7, or 8. Under similar conditions, 95% of 1-adamantyl-2-(4-methoxyphenyl)ethene 10 or 80% of 1-(4-oxoadamantyl)-2-(4-methoxyphenyl)ethene 12 also can be easily prepared by using 1-iodoadamantane 9 or 5-iodo-2-adamantanone 11 and 2.

📜 SIMILAR VOLUMES

ChemInform Abstract: Novel Synthesis of
ChemInform Abstract: Novel Synthesis of Alkenes via Triethylborane-Induced Free-Radical Reactions of Alkyl Iodides and β-Nitrostyrenes.
✍ Ju-Tsung Liu; Yeong-Jiunn Jang; Yuh-Kuo Shih; Shin-Ru Hu; Cheng-Ming Chu; Ching- 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

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