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Novel synthesis of 2′-O-methylguanosine

✍ Scribed by Suetying Chow; Ke Wen; Yogesh S. Sanghvi; Emmanuel A. Theodorakis

Book ID: 108477481
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 141 KB
Volume: 13
Category: Article
ISSN: 0960-894X
DOI: 10.1016/s0960-894x(03)00291-9

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and N; the bonding situations in 6 and 7 are rather similar. As suggested by the formal structure 9, a planar form would be expected to benefit from the Hiickel271 character of the four-membered ring. Nevertheless, 9 is 14.6 kcal/ mol less stable than 7 with the larger 6-31G\* basis set (13.2 kcal/