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Novel Synthesis of 2′-O-Methylguanosine.

✍ Scribed by Suetying Chow; Ke Wen; Yogesh S. Sanghvi; Emmanuel A. Theodorakis

Book ID: 101946812
Publisher: John Wiley and Sons
Year: 2003
Weight: 100 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200337175

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and N; the bonding situations in 6 and 7 are rather similar. As suggested by the formal structure 9, a planar form would be expected to benefit from the Hiickel271 character of the four-membered ring. Nevertheless, 9 is 14.6 kcal/ mol less stable than 7 with the larger 6-31G\* basis set (13.2 kcal/