✦ LIBER ✦

Novel sulfur-nitrogen-fluorine compounds : synthesis and properties of SF5NHF, SF5NClF and SF4NF

✍ Scribed by Darryl D. DesMarteau

Book ID: 104150803
Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 27 KB
Volume: 16
Category: Article
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)84091-9

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✦ Synopsis

Using reactions developed for the synthesis of CF2=NF, CF_,NClF and CF3NHF from ClCrN, F3SrN can now be converted in high yield to the analogous sulfur compounds, SF4=NF, SFSNClF and SF5NHF. N-fluorotetrafluorosulfurimine is the simplest sulfur(W) imine and is a rigid molecule.

Details on the synthesis and properties of these novel compounds will be presented.

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