Laurallene (L), a new brominated cyclic ether having a terminal allene moiety, has been isolated as a main constituent from the marine red alga Laurencia nipponica Yamada (Rhodomelaceae, Rhodophyta) and its structure was determined by its physical and chemical properties.
Novel skeletal bromo ether from the marine alga, Laurencia nipponica yamada
β Scribed by Teruaki Suzuki; Akio Furusaki; Nobuhiro Hashiba; Etsuro Kurosawa
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 225 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Red alga, Laurencia nipponica Yamada, is unique in the various biosynthesis of halogenated Cl5 non-terpenoids having the conjugated enyne (2) related to laurediol (3), chamigrene derivatives (4), cuparene derivatives (5) and methylrearranged sesquiterpenoids (6). In our continuing study of the neutral essential oil from this alga, we have isolated novel skeletal bromo ether (I) (acetal),
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The absolute configuration of cycloeudesmol, isolated from the red alga Lauren&a nipponica Yamada and Chondria oppositiclada Dawson, is determined by the crystallographic study. In our previous report'), the structure of isocycloeudesmol, C15HZ60, isolated from L. nipponica Yamada, has been proposed
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