𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Novel rearrangements in the steroid series

✍ Scribed by G. Teutsch; C. Lang; R. Smolik; J.P. Mornon; J. Delettré

Book ID
103397549
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
216 KB
Volume
22
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A novel rearrangement of steroidal α-hyd
A novel rearrangement of steroidal α-hydroxy oximes
✍ Dušan Miljković; Katarina Penov-Gaši; Evgenija Djurendić; Marija Sakač; Ljubica 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 80 KB

By the action of acidic titanium trichloride upon 16..oximino-17ct-benzyl-17l~-hydroxy derivatives in the androstane and estrane series the 16-oxo-1713-bcnzyl-17cc-hydroxy derivatives 6 and 7 with inversed configuration at C~7 were obtained. A mechanism for this novel rearrangement is proposed.

Steroids LXXVII. A novel rearrangement i
Steroids LXXVII. A novel rearrangement in an alcohol-lead tetraacetate reaction
✍ David Rosenthal; Constance F. Lefler; Monroe E. Wall 📂 Article 📅 1965 🏛 Elsevier Science 🌐 French ⚖ 182 KB

the first observation of a 1,2 migration of an alkyl group from carbon to oxygen during the course of a lead tetraacetatealcohol oxidation. Previous oxidations of this type have yielded either cyclic ethers' which are formed by the attack of the activated hydroxyl group on proximate carbon atoms or