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A novel rearrangement of steroidal α-hydroxy oximes

✍ Scribed by Dušan Miljković; Katarina Penov-Gaši; Evgenija Djurendić; Marija Sakač; Ljubica Medić-Mijačević; Vjera Pejanović; Slobodanka Stanković; Dušan Lazar

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
80 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

By the action of acidic titanium trichloride upon 16..oximino-17ct-benzyl-17l~-hydroxy derivatives in the androstane and estrane series the 16-oxo-1713-bcnzyl-17cc-hydroxy derivatives 6 and 7 with inversed configuration at C~7 were obtained. A mechanism for this novel rearrangement is proposed.

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