Novel Reactivity of SeO 2 with 1,3-Dienes: Selenophene Formation
β Scribed by Nguyen, Truc M.; Guzei, Ilia A.; Lee, Daesung
- Book ID
- 121367936
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 143 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The kinetics of the reactions of 1,2βdiazaβ1,3βdienes **1** with acceptorβsubstituted carbanions **2** have been studied at 20βΒ°C. The reactions follow a secondβorder rate law, and can be described by the linear free energy relationship logβ__k__(20βΒ°C)=__s__(__N__+__E__) [Eq.β (1)]. Wit