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ChemInform Abstract: A Novel Reactivity of SeO2 with 1,3-Dienes: Formation of syn 1,2- and 1,4-Diols via a Facile C—Se Bond Oxidation.

✍ Scribed by Truc M. Nguyen; Daesung Lee

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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The novel and versatile cyanomethyl 2amino-4-methylthiazolyl ketone (5) was prepared by treatment of bromomethyl 2-amino-4-methyl thiazolyl ketone (4) with potassium cyanide. Reaction of 5 with heterocyclic diazonium salts 6a,b and 10 afforded the corresponding hydrazones 7a,b and 11, respectively.