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Novel reactions of the iron(III) tetraphenylporphyrin π cation radical with pyridine

✍ Scribed by Krystyna Rachlewicz; Lechosław Latos-Grażyński

Book ID: 103569163
Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 59 KB
Volume: 51
Category: Article
ISSN: 0162-0134
DOI: 10.1016/0162-0134(93)85070-o

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## Abstract Addition of aryl Grignard reagents to an iron(III) tetraphenylporphyrin π cation radical, [(TPP⋅)Fe^III^Cl] (SbCl~6~), in dichloromethane solution at 202 K yields a mixture of σ‐phenyl iron(IV) tetraphenylporphyrin, [(TPP)Fe^IV^(Ph)] (SbCl~6~), and σ‐phenyl iron(III) tetraphenylporphyri