Novel Radicals from the Reaction of Phospholes with Potassium
โ Scribed by Dr. Colin Thomson; D. Kilcast
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 229 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
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The kinetics and mechanism of the reaction of BrO with dimethylsulfide [ DMS) have been studied by the mass spectrometric discharge-flow method in the temperature range (233-320) K and at a total pressure around 1 torr. The temperature dependence of the reaction rate constant k , = [ 1.5 ? 0 4 ) X 1
A rate constant for the epoxidation of acrolein by acetylperoxyl radicals has been determined to be k 4 ฯญ (1.3 ฯฎ 0.9) ฯซ 10 4 dm 3 mol ฯช1 s ฯช1 at 383 K, which is anomalously fast in comparison with the epoxidation of alkenes. Abstraction of the acyl hydrogen atom from acrolein by acetylperoxyl radica