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Novel Polycyclic Phosphanes and Arsanes: P11(SiMe3)3 and As7(SiMe3)3

✍ Scribed by Prof. Dr. Hans Georg von Schnering; Priv.-Doz. Dr. Dieter Fenske; Dr. Wolfgang Hönle; Dr. Michael Binnewies; Dr. Karl Peters


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
134 KB
Volume
18
Category
Article
ISSN
0044-8249

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FC(SiMe3)3 and FC(SiMe3)2SnBu3: a novel
✍ Masaki Shimizu; Takeshi Hata; Tamejiro Hiyama 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 231 KB

Reaction of fluorotris(trimethyisilyl)methane and aldehydes is catalyzed by KF/18-Cr-6 to give 1,3disubstituted 2-fluoro-2-propen-l-ols in one pot. On the other hand, Sn-Li exchange of bis(trimethylsilyl)fluoro(tributylstannyl)methane with BuLi and subsequent treatment with an aldehyde afforded 1flu