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Synthesis and Structure of P7[Si(SiMe3)3]3(Tri(hypersilyl)heptaphosphanortricyclane)

✍ Scribed by Harald Siegl; Werner Krumlacher; Karl Hassler


Publisher
Springer Vienna
Year
1999
Tongue
English
Weight
104 KB
Volume
130
Category
Article
ISSN
0026-9247

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The two hypersilylcuprates LiCu 2 Hyp 3 (2) and [Li 7 (O t Bu) 6 ][Cu 2 Hyp 3 ] (3) (Hyp = Si(SiMe 3 ) 3 ) were synthesized by reactions of unsolvated lithium hypersilanide, Li-Hyp with hypersilylcopper and CuO t Bu, respectively. Both contain the novel A-frame trihypersilyldicuprate anion [Cu 2- Hy