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Novel poly(aryl ether ketone)s exhibiting liquid crystallinity

โœ Scribed by S.J. Zhang; D.C. Yang; Stephen Z.D. Cheng; Y.B. Zheng; Z.W. Wu; R. Yosomiya


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
36 KB
Volume
49
Category
Article
ISSN
0323-7648

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โœฆ Synopsis


Novel poly(aryl ether ketone)s were synthesized by nucleophilic substitution reactions of difluoromonomer with 4,49-biphenol and substituted hydroquinone. The results showed that the novel polymers exhibited multiple phase transitions and formed optical birefringence textures above their melting transitions.


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Several kinds of commercially available polymers of the type poly(oxy-1,4-phenylenecarbonyl-1,4-phenylene) were sulfonated by reaction with mixtures of sulfuric acid and oleum. The ether/carbonyl group ratio of the polymer chain varied from 0.67 to 2.0. With decreasing amounts of ether links in the