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Novel Phthalocyanines with Aza Crown Ether Moieties

✍ Scribed by Ahsen, Vefa ;Gürek, Ayşegül ;Musluo??lu, Emel ;Bekāro??lu, Özer

Book ID
101818296
Publisher
Wiley (John Wiley & Sons)
Year
1989
Tongue
English
Weight
163 KB
Volume
122
Category
Article
ISSN
0009-2940

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✦ Synopsis

Aza crown ethers / (Phtha1ocyaninato)copper complex / Phthalocyanines, water-soluble A monoaza crown ether substituted @hthalocyaninato)copper(1I) complex 2 and its water-soluble quaternary ammonium salt 3 were prepared from the corresponding dibromomonoaza crown ether derivative 1 and CuCN in pyridine.

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A facile route to a novel aza-crown ethe
A facile route to a novel aza-crown ether incorporating three thiophene moieties
✍ Joan Halfpenny; Phillip B Rooney; Zachary S Sloman 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 100 KB

The preparation of the ®rst of a novel type of large thiophene-containing aza-crown ether is reported. The macrocycle is synthesised by linking a 3,4-dialkoxythiophene moiety with two 3-hydroxythiophene units and ring closure is eected by reaction with piperazine via the Mannich reaction.