Novel photochemical rearrangement of aryl-6,7-dioxabicyclo[3.2.2]nona-3,8-dien-2-one into tricyclic lactone
โ Scribed by Tezuka, T.; Miyamoto, R.; Mukai, T.; Kabuto, C.; Kitahara, Y.
- Book ID
- 127287026
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 388 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
It has been shown that the enone-x interaction (shown by a) is inherent to the excited state of homoconjugated cyclic dienones (la-h), which brings about the photo-Cope rearrangement probably through thier singlet states, giving rise to the formation of theketenes(2ah h)(1,2,3). Recently, however, S
The discovery' that bicycle [ 5.1.01 o&a-2, S-diene (3,4-hometropilidene, I) undergoes a rapidly reverisible, degenerate Cope roarrangement has stimulated considerable theoretical interest. The generality of such behavior hae recently been put to test by the Syntheal11 of trtcyclo [ 3.3.2. 04' 6] de