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Additions and Corrections - A Novel Photochemical Rearrangement of Aryl-6,7-dioxabicyclo[3.2.2]nona-3,8-dien-2-one into Tricyclic Lactone

✍ Scribed by Tezuka, T.; Miyamoto, R.; Mukai, T.; Kabuto, C.; Kitahara, Y.


Book ID
127090971
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
269 KB
Volume
95
Category
Article
ISSN
0002-7863

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Mechanism of the photo-rearrangement of
✍ T. Tezuka; R. Miyamoto; M. Nagayama; T. Mukai πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 226 KB

It has been shown that the enone-x interaction (shown by a) is inherent to the excited state of homoconjugated cyclic dienones (la-h), which brings about the photo-Cope rearrangement probably through thier singlet states, giving rise to the formation of theketenes(2ah h)(1,2,3). Recently, however, S