## Abstract A kinetic study of the oxidation of allyl alcohol by potassium hexacyanoferrate (III) in the presence of palladium (II) chloride is reported. The reaction was observed by measuring the disappearance of the potassium hexacyanoferrate (III) spectrophotometrically. The reaction is first or
โฆ LIBER โฆ
Novel parallel path mechanism for the oxidation of allyl alcohol by aqueous palladium(II) chloride
โ Scribed by Zaw, K.; Lautens, M.; Henry, P. M.
- Book ID
- 127024242
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 387 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0276-7333
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Further mechanistic studies on the PdCl,(pyridine)-catalytic system in aqueous solution are described using the tetrasubstituted allylic alcohol, (E)-2-methyl-d,-4-methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-o1, 3a, and the trisubstituted allylic alcohol, (E)-4-Methyl-1,1,1,5,5,5-hexafluoro-3-penten-2-