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Novel oxidative cleavage of C17C20 bond in pregnane by a Pseudomonas sp

✍ Scribed by Dhar, Aloke; Samantha, Timir B.

Book ID
123055494
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
248 KB
Volume
44
Category
Article
ISSN
0960-0760

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Alkyne and ketone induced novel cleavage
Alkyne and ketone induced novel cleavage of a CC bond and a CSi bond in zirconacyclobutene–silacyclobutene fused ring compounds
✍ Tao Yu; Liang Deng; Changjia Zhao; Zhiping Li; Zhenfeng Xi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 244 KB

Novel cleavage patterns of C C bonds and C Si bonds were achieved via alkyne-or ketone-induced reactions of zirconacyclobutene-silacyclobutene fused ring compounds; thermodynamically favored six-membered zirconacyclohexadiene derivatives were formed in excellent yields from the four-membered zircona