Novel oxidation of 1,2-Dibenzylhydrazines with carbon tetrachloride
β Scribed by Kunio Kano; Jean-Pierre Anselme
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 139 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The photolysis of azocyclopentane in the presence of cyclopentaneβcarbon tetrachloride mixtures has been investigated in the gas phase. Product analysis data have been used to determine the Arrhenius parameters for the reactions The rate data for chlorine atom abstraction from CCl~4~
## The reaction (3) i-CpF, + CCli-C3F&l + CCl3 was investigated in the gas phase over the range 80-225Β°C using the photolysis of heptafluoroisopropyl iodide as the source of radicals. The rate constant, based on the value of 1013 36 cm3 mol log(k3/cm3 mol-' s-l) = (13.10 2 0.20) -(14000 \* 280)/0