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Novel one step synthesis of epoxides from β-hydroxy-selenides and sulfides

✍ Scribed by J.L. Laboureur; W. Dumont; A. Krief


Book ID
104233860
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
242 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


Epoxides

are stereoselectively prepared in one step from %-hydroxy selenides and 6-hydroxy sulfides in a process which involves dichlorocarbene

We have recently shown that &hydroxy selenides and fl-hydroxysulfides possessing two alkyl residues on the carbon bearing the selenenyl or the sulfenyl group rearrange to ketones in the presence of silver tetrafluoroborate,


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