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ChemInform Abstract: Magnesium Chloride-Catalyzed Thiolysis of Epoxides: Synthesis of β-Hydroxy Sulfides.

✍ Scribed by Rashmi Rani; Shankha Pattanayak; Jyoti Agarwal; Rama Krishna Peddinti

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A mild and efficient method for the preparation of the title compounds (III) and (V) using a nontoxic, stable and inexpensive catalyst is developed.

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Synthesis of β-Hydroxy Sulfides via Thio
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## Abstract __S__‐Alkylisothiouronium salt as a nontoxic, odorless and simply operational alternative of thiol was reacted with different kinds of epoxides in basic aqueous medium at room temperature affording the __β__‐hydroxy sulfides with high regioselectivity in excellent yields.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: One-Pot Synthesis o
ChemInform Abstract: One-Pot Synthesis of β-Amino/β-Hydroxy Selenides and Sulfides from Aziridines and Epoxides.
✍ Venkataraman Ganesh; Srinivasan Chandrasekaran 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

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