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Novel N,N,O Scorpionate Ligands and Transition Metal Complexes Thereof Suitable for Polymerisation

✍ Scribed by Eike Hübner; Gazi Türkoglu; Marion Wolf; Ulrich Zenneck; Nicolai Burzlaff


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
294 KB
Volume
2008
Category
Article
ISSN
1434-1948

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## Abstract **The cover picture shows** the constellation scorpio (lat. scorpius), which symbolises the heteroscorpionate ligands described in the article. To the left, a complex bearing such a heteroscorpionate ligand is fixed on a solid phase. In the back, another ligand with a linker for immobil

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The chemical behavior of two bis(3,5-dialkylpyrazol-1-yl)acetic acids and their coordination properties towards ZnCl 2 and FeCl 2 was studied. Reaction of bis(3,5-dimethylpyrazol-1-yl)acetic acid (bdmpza) (1) with ZnCl 2 and FeCl 2 gave the 2:1 complexes [(bdmpza) 2 Zn] (4) and [(bdmpza) 2 Fe] (5).