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Novel N-heterocyclic-carbene–rhodium complexes as hydrosilylation catalysts

✍ Scribed by Murat Yiğit; Ismail Özdemir; Bekir Çetinkaya; Engin Çetinkaya

Book ID
108211576
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
220 KB
Volume
241
Category
Article
ISSN
1381-1169

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Synthesis of novel rhodium-xylyl linked
Synthesis of novel rhodium-xylyl linked N-heterocyclic carbene complexes as hydrosilylation catalysts
✍ Ismail Özdemir; Serpil Demir; Onur Şahin; Orhan Büyükgüngör; Bekir Çetinkaya 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 412 KB 👁 2 views

## Abstract Reaction of __ortho__‐xylylbis(__N__‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(__N__‐butylimidazolinium) and __para__‐xylylbis(__N__‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(__N__‐butylimidazolinium) salts with KOBu^__t__^ and [RhCl(COD)]~2~ yields __ortho__‐ and __para__‐xylyl