Mass spectral rearrangements of siliconi
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William P. Weber; Raymond A. Felix; Alvin K. Willard
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Article
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1970
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Elsevier Science
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French
โ 179 KB
We have observed in the mass spectrum of 1-phenyl-Z-trimethylsilylethanel a novel intramolecular rearrangement of the phenyl group from carbon to a positively charged silicon center. The base peak at m/e = 73 is due to the trimethylsiliconium ion, while the peak at m/e = 163 results from loss of a