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Mass spectral rearrangements of siliconium ions. Migration of electronegative groups from carbon to silicon

โœ Scribed by Weber, William P.; Felix, Raymond A.; Willard, Alvin K.


Book ID
127212875
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
213 KB
Volume
91
Category
Article
ISSN
0002-7863

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Mass spectral rearrangements of siliconi
โœ William P. Weber; Raymond A. Felix; Alvin K. Willard ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 179 KB

We have observed in the mass spectrum of 1-phenyl-Z-trimethylsilylethanel a novel intramolecular rearrangement of the phenyl group from carbon to a positively charged silicon center. The base peak at m/e = 73 is due to the trimethylsiliconium ion, while the peak at m/e = 163 results from loss of a