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Novel ligands derived from S-tyrosine for the enantioselective addition of diethylzinc to aldehydes

✍ Scribed by Juliane Beliczey; Guido Giffels; Udo Kragl; Christian Wandrey

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 107 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(97)00150-x

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New nitrogen-containing ligands derived from the (1R,2R)-trans-cyclohexanediamine chiral core unit have been synthesized and fully characterized. Their catalytic activity was tested in the asymmetric addition of diethylzinc to aldehydes leading to the respective secondary alcohols with enantioselect