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Novel intramolecular [4 + 2] cycloaddition reactions of enamines and enamides with unactivated dienes

✍ Scribed by Martin, Stephen F.; Tu, Chih-Yun; Chou, Ta-Shue


Book ID
127270039
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
882 KB
Volume
102
Category
Article
ISSN
0002-7863

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Intramolecular [4+2] cycloaddition react
✍ Stephen F. Martin; Ta-shue Chou; Chih-yun Tu πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 259 KB

An attempt to utilize a new strategy for alkaloid synthesis which features the intramolecular [4+2] cycloaddition of enamines and enamides for the construction of the tetracyclic spiroamine skeleton characteristic of the ~rythrina alkaloids was unsuccessful, unexpectedly giving a bridged cycloadduct