Intramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and Dienes.
β Scribed by Martin E. Hayes; Hiroshi Shinokubo; Rick L. Danheiser
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 28 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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Steric Hindrance Facilitated Synthesis of Enynes and Their Intramolecular [4 + 2] Cycloaddition with Alkynes. -The unexpected formation of enediyne (IV) under Sonogashira-coupling conditions is explained by a regioselective Pd-catalyzed insertion reaction facilitated by steric hindrance resulting in
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