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Novel Intercalation Compounds of MoS 2

โœ Scribed by Powell, Anthony V.; Kosidowski, Laura; McDowall, Andrew

Book ID
120471095
Publisher
Taylor and Francis Group
Year
2000
Tongue
English
Weight
257 KB
Volume
341
Category
Article
ISSN
1058-725X

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The structure of the intercalation compound K 0.7 MoS 2 as well as of its hydrated (K 0.3 (H 2 O) y MoS 2 ) and oxidation (1T-MoS 2 ) derivatives were studied by means of selected area electron di4raction (SAED). All the derivatives are shown to have superstructures related to the structure of 2H-Mo

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2H-MoS2 is a semiconductor with a hexagonal layered structure. Each Mo atom is prismatically coordinated by six S atoms. Our in situ X-ray diffraction results indicate that, upon intercalation, the MoS2 host lattice undergoes a first order phase transition in which the Mo coordination changes from t