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Novel initiating systems of the type AIR3-acylic peroxide

✍ Scribed by Milovskaya, E. B. ;Zhuravleva, T. G. ;Zamoyskaya, L. V.

Book ID
105340081
Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
697 KB
Volume
16
Category
Article
ISSN
0449-2994

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Mechanism of the initiation step in the
Mechanism of the initiation step in the systems air3β€”acyl peroxideβ€”polar monomer
✍ E.B. Milovskaya; L.V. Zamoyskaya; S.I. Vinogradova πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 English βš– 527 KB

The kinetics of the polymerization of methyl methacrylate, initiated by AIR3-acyl peroxide, have been investigated. The polymers were of relatively low molecular weight because of a great activity of the complex A1R3.M as a transfer agent. The value Ct for AI (i-Bu)a/MMA was found to be 0" 6 at 0 Β°.