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Novel generation of azomethine ylide from N-(α-silylbenzyl)amide by silicon shift: an equivalent of nitrile ylide

✍ Scribed by Mitsuru Ohno; Mitsuo Komatsu; Hiroyuki Miyata; Yoshiki Ohshiro

Book ID
104225911
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
262 KB
Volume
32
Category
Article
ISSN
0040-4039

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✦ Synopsis

Azomethine ylides were generated from N-(a-silylbenzyl)amides by thermal silicon shift to the oxygen and trapped with dipolarophiles to give the same products as those from the corresponding nitrile ylides via elimination of silanol.

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Novel generation and cycloaddition of N-
Novel generation and cycloaddition of N-silylated azomethine ylides from α-silylimidates and trifluorosilane
✍ Ken-Ichi Washizuka; Satoshi Minakata; Ilhyong Ryu; Mitsuo Komatsu 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 458 KB

The Generation of N-silylated azomethine ylides was achieved by the reaction of asilylimidates and trifluorophenylsilane. The generated azomethine ylides can b¢ regarded as synthetic equivalents of nitrile ylides since they have an alkoxy group which may serve as a leaving group. Cycloaddition with

ChemInform Abstract: Novel Generation an
ChemInform Abstract: Novel Generation and Cycloaddition of N-Silylated Azomethine Ylides from α-Silylimidates and Trifluorosilane.
✍ Ken-Ichi Washizuka; Satoshi Minakata; Ilhyong Ryu; Mitsuo Komatsu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

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