Novel formation of anti-Bredt olefins from 2,3,4,5,6,7-hexahydro-1,6-methano-1H-4-benzazonin-7-ols
β Scribed by Shiotani, Shunsaku.; Kometani, Tadashi.; Kurobe, Akira.; Mitsuhashi, Kemmotsu.
- Book ID
- 126029695
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 446 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Z-Substituted-1,2,3,4,5,6-hexahydro-3-bemwxine-4, 6diones(la-d) and 2-methoxy-2,5,6,7-tetrahydro+ benxamnine-1,3dione 8 were synthesii thro@ an oxklative ring expansion reaction of 6-methylthio-7-substiituted-benzo(a] octem (2a-d ) and 7-methylthio%-methoxy-benzo[a]nonem 7 with sodium periodate in i
The title compound, C 18 H 22 N 2 O 3 , consists of a tetracyclic ring system containing an azocino skeleton with a dimethoxyethyl group as a substituent. The benzene and five-membered rings are nearly coplanar, with a dihedral angle of 1.26 (8) . In the crystal structure, intermolecular N-HΓ Γ ΓO h