Novel double [6 + 4] cycloaddition of tropone to dimethylfulvene
โ Scribed by Houk, K. N.; Luskus, L. J.; Bhacca, N. S.
- Book ID
- 120775361
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 411 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
We recently reported the periaelective formation of 2:l adduct && in the reaction of tropone with dimethylfu1vene.l This observation of an unprecedented reaction of a fulvene as a 6~ addend has led us to investigate further the mechanism of this reaction.
Beceived inlISA 6 Jnly1970; received inI0Kfor~blicetiom 3 Septe&er IgO) Tbe 1,3-dipolar cycloadditioa reectioe has been the sobject of tiaz eabaustive ard elegant iaveatigationa of Eluiagen sad w-a~rkers.~ Tkse reactions shap all the cbarecteristics of coacerted reactions, iacluding stereospecificit