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Novel Design of a Pentacyclic Scaffold as Structural Mimic of Saframycin A.

✍ Scribed by Chi Wi Ong; Yu An Chang; Jing-Yun Wu; Chien-Chung Cheng

Publisher
John Wiley and Sons
Year
2004
Weight
58 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract Electrochemical oxidation of 2,4‐dimethylphenol directly provides pentacyclic systems being generated by an oxidative trimerization. The major pentacyclic scaffold is exclusively formed as a single diastereoisomer and is easily isolated. Three further pentacyclic compounds which occur i