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Novel Concerted Fragmentation upon Alcoholysis of a Urazole

โœ Scribed by Wei, Yanjun; Lemal, David M.


Book ID
126961097
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
65 KB
Volume
6
Category
Article
ISSN
1523-7060

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โœ Pier Andrea Gatti; Stefania Gagliardi; Alberto Cerri; Carlo Farina ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 199 KB

Two novel fragmentations of the skeletal back bone of bafilomycin At are reported. These reactions occur under mild conditions and afford new bafilomycin analogues lacking 4 and 8 carbon atoms of the letrahydropyran ring, respectively.