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Novel Chiral Ferrocenyl-imino Phosphine Ligands and Their Use in Palladium-Catalyzed Allylic Alkylations.

โœ Scribed by Pierluigi Barbaro; Claudia Bianchini; Giuliano Giambastiani; Antonio Togni


Publisher
John Wiley and Sons
Year
2004
Weight
124 KB
Volume
35
Category
Article
ISSN
0931-7597

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Effective Chiral Ferrocenyl Phosphine-Th
โœ Hong Yee Cheung; Wing-Yiu Yu; Terry T.โ€…L. Au-Yeung; Zhongyuan Zhou; Albert S.โ€…C. ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 454 KB ๐Ÿ‘ 2 views

## Abstract magnified image Chiral ferroceneโ€derived phosphineโ€thioether mixed donor ligands supported by heterocycles effected the palladiumโ€catalyzed enantioselective allylic alkylations with excellent yields and enantioselectivities (up to 96% __ee__). With cyclic and unsymmetrical allylic acet