Novel Carbonyliridium and -rhodium Complexes Containing 2,6-Bis[(4′S)-4′-isopropyloxazolin-2′-yl]pyridine (iPr-pybox) and 2,6-Bis[(4′R)-4′-phenyloxazolin-2′-yl]pyridine (Ph-pybox) Ligands
✍ Scribed by Darío Cuervo; Josefina Díez; M. Pilar Gamasa; José Gimeno; Paloma Paredes
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 220 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-1948
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Treatment of complex trans-[RuCl(2)(eta(2)-C(2)H(4))[kappa(3)-N,N,N-(R,R)-Ph-pybox]] [(R,R)-Ph-pybox = 2,6-bis[4'-(R)-phenyloxazolin-2'-yl]pyridine] with phosphines or phosphites in dichloromethane at 50 degrees C leads to the formation of novel ruthenium(II)-pybox complexes trans-[RuCl(2)(L)[kappa(
Reactions of [RhClL] (L,=diolefin or (CO)(PPh,)) with the deprotonated form of the ligand 3,5bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh&)(bpt)]. Cationic, mono-and dinuclear species of formulae [Rh&.)(Hbpt)]+, [{Rhb}\*(bpt)]+ and [{Rh&.}@bpt)]\*+, where b=diolefi
The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act